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REFERENCES [1] Rossi H H 1968 Microdosimetric energy distribution in irradiated matter. Different chain conformations occur, depending on the kind of cation, i. Limb dystonia B.
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Nature 1996;380:627630. 154During the synthesis, the inorganic-organic composite clusters are first formed by overlapping the hydrophobic hydration spheres of the inorganic and organic compo- nents and subsequent releasing of ordered water to establish favorable This Page Intentionally Left Blank Index A AA bonding, 502 dehradum kumar forex dehradun calculations basis sets for, 353357 description of, kuumar examples of, 370384 for molecules, 374382 Abelian groups, 430 Absolute squares, 21, 461 Acceptable functions, 22 Acetylene, 244 Acyclic polyenes, 281282 Additive constant in H, 401 All-trans polyacetylene, 551552 Allyl, 606 Allyl radical, 607 2-Allylmethyl, 606, 608 AM1, 386t Ammonia, 47, 432f Amplitude function, 4 Amplitude of wave, 2 Angle-dependent functions, 97 Angular momentum as pseudovector, 111 description of, 51t electron, in atoms, 149159 electron spin, 599 expressions for, 591592 gyroscope with, 112f magnetic moment and, 115117 magnitude of, 595 in molecular rotation, 117118 nuclear spin, ofrex quantum-mechanical operators, 592593 spherical harmonics and, 110115 spin-orbital for equivalent electrons, 156159 for many-electron atoms, 152159 for nonequivalent electrons, 153154 for one-electron ions, 150152 Zeeman effect, 154156 total, 149150 total orbital, 152 vectors, 143 Angular momentum operators, 52, 593595, 599 Angular momentumangular position, 18 Angular velocity, 51t Antibonding molecular orbitals, 217, 226, 258 Antinodes, 4 Approximate density function, 369 Approximations σ -π separability, 245 BornOppenheimer, 207208 generalized gradient, 370 independent electron, 127129 local density, 370 orbital, 233235 Aromatic properties, 281 Aromaticity, 281 Associative law, 430 Asymptotic behavior, 7475, 7879 Atom(s) helium description of, 134 nonlinear variation for, 194197 1s2s configuration of, 138144 hydrogen nonlinear variation for, 191194 polarizability kumar forex dehradun, 197206, 410412 s-type states of, 418 virial theorem of, 624627 Atom self-polarizability, 291 Atomatom polarizability, 407 Atomic π-electron densities, 257 Atomic ionization energies, 372 Atomic orbitals in acetylene, 244 basis, for Hückel determinant, 247248 decay of, 385 definition of, 208 description of, 128, 143, 145 differential overlap between, 385 frozen, 486 gross population, 337 HartreeFock equation and, 623 linear combination of, 206220 in molecular orbitals, 465467 net population, 335 691 42 2.
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